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15 June 2018, 13:31 | Updated: 15 June 2018, 14:48
The Italian tenor joined the pop star on stage during his world tour, to sing their duet 'Perfect Symphony'.
Last night (14 June), Ed Sheeran and Andrea Bocelli sang 'Perfect Symphony' live together for the first time at Wembley Stadium.
When Ed released the Italian version of his single on 15 December last year, the music video became the highest trending that day on YouTube.
Andrea Bocelli already made the headlines this week after scooping the Classic BRITs Icon Award at the Classic BRITs on Wednesday.
Read more: What time will the Classic BRIT Awards be on ITV?
Plus, in October Bocelli will release Sì, his first album of new material in 14 years. He will perform the first single from the album, 'Qualcosa' when the Classic BRIT Awards are broadcast on Sunday.